Methyl transfer from methylcobalamin to diaquocobinamide.

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Methyl transfer from methylcobalamin to diaquocobinamide.

The transfer of the methyl group from methylcobalamin to diaquocobinamide in aqueous solution has been demonstrated by proton, carbon-13, and phosphorus-31 nuclear magnetic resonance spectroscopy. The products of this reaction are aquocobalamin and the methylaquocobinamides. Dicyanocobinamide and the cyanoaquocobinamides do not serve as methyl acceptors, while ligands such as pyridine and histi...

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Platinum-catalyzed phenyl and methyl group transfer from tin to iridium: evidence for an autocatalytic reaction pathway with an unusual preference for methyl transfer.

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ژورنال

عنوان ژورنال: Proceedings of the National Academy of Sciences

سال: 1984

ISSN: 0027-8424,1091-6490

DOI: 10.1073/pnas.81.9.2698